- "Solarian Saber" plays when Star and her friends arrive to save Eclipsa from the Solarian Warrior.
- "Greatest Warriors of Mewni" plays when Star's friends introduce themselves to Eclipsa.
- "For Mewni" plays when Star and her friends charge down the cliff to face the Solarian Warrior.
- "Misty Mewni Town" plays when Star and her friends begin their search for the Solarian Warrior in the abandoned Monstertown.
- "Parkour Man" plays when Kelly, Talon Raventalon, and Quirky Guy search for the Solarian Warrior, and the Warrior wounds Quirky with its sword.
- "Compendium of Magical Elements" plays when Eclipsa and Janna consult the Compendium of Magical Elements for answers on Globgor's condition.
- "Kelly and Pigeon Down" plays when the Solarian Warrior incapacitates Kelly and Rich Pigeon with its sword.
- "Show Her Your Heart" plays when Pony Head inspires Star with words of encouragement and Star casts "Rainbow Kaiju Battle Armor".
- "Mecha Rainbow Star Vs. Mina" plays when Star faces off against the Solarian Warrior.
- "The Spell That Has No Name" plays when Eclipsa casts the "Spell With No Name" and defeats the Solarian Warrior.
- "Starco Reunion" plays when Star reunites with Marco.
- "Mina and Her Army" plays when Mina Loveberry arrives with her army of hundreds of Solarian Warriors.
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